材料期刊网

INTERGRANULAR CORROSION AND PHOSPHOR SEGREGATION AT GRAIN BOUNDAR1FS OF NON-SENSITIZED SUPERPURE AUSTENITIC STAINLESS STEEL 00Cr25Ni22Mo2N

FANG Yaohua Nanjing Institute of Chemical Technology , Nanjing , ChinaXU Yuan ZHANG Wenqi University of Science and Technology Beijing , Beijing , China FANG Yaohua Associate Professor , Dept.of Applied Chemistry , Nanjing Institute of Chemical Technology , Nanjing 210009 , China

金属学报(英文版)

The corrosion behaviour and mechanism of superpure austenitic stainless steel 00Cr25Ni22Mo2N in urea processing environment was studied using metallography,SEM, TEM,SIMS and AES techniques.The results show that the gas extraction tube made of non-sensitized 00Cr25Ni22Mo2N steel suffered intergranular corrosion.Corrosive media penetrated not only into the tube wall through grain boundaries but also expanded from the boundary towards the interior of the grain.Neither depletion of Cr nor precipitates were found at the grain boundaries.However,P(and Si)was segregated at the grain boundaries to a great extent.Semiquantitative calculation indicates that the P content at the grain boundaries is about 25 wt-%,three orders of magnitude higher than the content within the grain.Sugges- tion is made that the potential difference between the grain and its boundary due to the segre- gation results in the observed intergranular corrosion.

关键词: superpure austenitic stainless steel , null , null

University of Science and Technology Beijing

JIA Shizhen University of Science and Technology Beijing , China.

材料科学技术（英）

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Abstracts of papers from Journal of University of Science and Technology Beijing

稀有金属（英文版）

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CORRELATION BETWEEN STRESS COMPONENTS AND STRESS CORROSION CRACKS IN BRASS Lecturer,Department of Materials Physics,University of Science and Technology Beijing,Beijing 100083,China

QIAO Lijie LIU Rui XIAO Jimei University of Science and Technology Beijing , Beijing , China

金属学报(英文版)

The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.

关键词: stress corrosion cracking , null , null , null

Huazhong University of Science and Technology(H.U.S.T)

材料科学技术（英）

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欢迎投稿、订阅《Journal of Wuhan University of Technology-Materials Science Edition》

武汉理工大学学报-材料科学版(英文版)

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Institute of Materials Science at Jilin University——A Brief Overview

WANG Yuming Institute of Materials Science , Jilin University , Changchun , 130023 , China

材料科学技术（英）

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CHINESE JOURNAL OF METAL SCIENCE & TECHNOLOGY

材料科学技术（英）

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Bibliography of Science and Technology of Rare EarthsPublished in China (2001)

稀土学报(英文版)

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Bibliography of Science and Technology of Rare EarthsPublished in China (2001)

稀土学报(英文版)

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